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A modified zone model for estimating equivalent room thermal capacity

Hua CHEN, Xiaolin WANG

《能源前沿（英文）》 2013年第7卷第3期页码 351-357 doi: 10.1007/s11708-013-0254-x

摘要： The zone model has been widely applied in control analysis of heating, ventilation and air conditioning (HVAC) systems to achieve a high building efficiency. This paper proposed a modified zone model which is much simpler in the HVAC system simulation and has the similar accuracy to the complicated simulation model. The proposed model took into consideration the effect of envelop heat reservoir on the room indoor temperature by introducing the thermal admittance of the inner surfaces of the building enclosure. The thermal admittance for the building enclosure was developed based on the building thermal network analytical theory and transfer function method. The efficacy of the proposed model was demonstrated by comparing it with the complicated model — heat balance method (HTB2 program). The predicted results from the proposed model well agreed with those from the complicated simulation. The proposed model can then make the HVAC system dynamic simulation much faster and more acceptable for control design due to its simplicity and efficiency.

关键词： room model thermal network analysis transfer function heating ventilation and air conditioning (HVAC) system simulation

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Prevention of surgical site infection under different ventilation systems in operating room environment

Zhijian Liu, Haiyang Liu, Hang Yin, Rui Rong, Guoqing Cao, Qihong Deng

《环境科学与工程前沿（英文）》 2021年第15卷第3期 doi: 10.1007/s11783-020-1327-9

摘要： Abstract • The effectiveness of four different ventilation systems was compared in depth. • Airflow and bacteria-carrying particles concentration were quantitatively analyzed. • Vertical laminar airflow with high airflow rate could not achieve desired effect. • Temperature-controlled airflow ventilation could guarantee air cleanliness. Biological particles in the operating room (OR) air environment can cause surgical site infections (SSIs). Various ventilation systems have been employed in ORs to ensure an ultraclean environment. However, the effect of different ventilation systems on the control of bacteria-carrying particles (BCPs) released from the surgical staff during surgery is unclear. In this study, the performance of four different ventilation systems (vertical laminar airflow ventilation (VLAF), horizontal laminar airflow ventilation (HLAF), differential vertical airflow ventilation (DVAF), and temperature-controlled airflow ventilation (TAF)) used in an OR was evaluated and compared based on the spatial BCP concentration. The airflow field in the OR was solved by the Renormalization Group (RNG) k-e turbulence model, and the BCP phase was calculated by Lagrangian particle tracking (LPT) and the discrete random walk (DRW) model. It was found that the TAF system was the most effective ventilation system among the four ventilation systems for ensuring air cleanliness in the operating area. This study also indicated that air cleanliness in the operating area depended not only on the airflow rate of the ventilation system but also on the airflow distribution, which was greatly affected by obstacles such as surgical lamps and surgical staff.

关键词： Operating room (OR) Bacteria-carrying particles (BCPs) Surgical site infections (SSIs) Ventilation

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一种模拟疏散流程的疏散时间计算方法

祝佳琰,张和平

《中国工程科学》 2006年第8卷第8期页码 73-76

摘要：

在工程实际中，通过人员安全疏散所需要的时间与人员安全疏散可用的时间进行比较来判断建筑的疏散设施能否满足突发情况下人员安全疏散的要求。将建筑的疏散设施抽象成网络的节点，从而将人员在建筑中的疏散流程简化成节点的串联系统模型，并联系统模型或者是串、并联系统组成的复杂模型，并给出了计算的方法。

关键词：人员疏散疏散设施串联模型并联模型

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Genomic and metabolomic analysis of with enhanced poly--glutamic acid production through atmospheric and room

《化学科学与工程前沿（英文）》 2022年第16卷第12期页码 1751-1760 doi: 10.1007/s11705-022-2211-x

摘要： Poly-γ-glutamic acid is an extracellular polymeric substance with various applications owing to its valuable properties of biodegradability, flocculating activity, water solubility, and nontoxicity. However, the ability of natural strains to produce poly-γ-glutamic acid is low. Atmospheric and room temperature plasma was applied in this study to conduct mutation breeding of Bacillus licheniformis CGMCC 2876, and a mutant strain M32 with an 11% increase in poly-γ-glutamic acid was obtained. Genome resequencing analysis identified 7 nonsynonymous mutations of ppsC encoding lipopeptide synthetase associated with poly-γ-glutamic acid metabolic pathways. From molecular docking, more binding sites and higher binding energy were speculated between the mutated plipastatin synthase subunit C and glutamate, which might contribute to the higher poly-γ-glutamic acid production. Moreover, the metabolic mechanism analysis revealed that the upregulated amino acids of M32 provided substrates for glutamate and promoted the conversion between L- and D-glutamate acids. In addition, the glycolytic pathway is enhanced, leading to a better capacity for using glucose. The maximum poly-γ-glutamic acid yield of 14.08 g·L^–1 was finally reached with 30 g·L^–1 glutamate.

关键词： ARTP mutagenesis Bacillus licheniformis poly-γ-glutamic acid metabolomics

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Perspective on gallium-based room temperature liquid metal batteries

《能源前沿（英文）》 2022年第16卷第1期页码 23-48 doi: 10.1007/s11708-022-0815-y

摘要： Recent years have witnessed a rapid development of deformable devices and epidermal electronics that are in urgent request for flexible batteries. The intrinsically soft and ductile conductive electrode materials can offer pivotal hints in extending the lifespan of devices under frequent deformation. Featuring inherent liquidity, metallicity, and biocompatibility, Ga-based room-temperature liquid metals (GBRTLMs) are potential candidates to fulfill the requirement of soft batteries. Herein, to illustrate the glamour of liquid components, high-temperature liquid metal batteries (HTLMBs) are briefly summarized from the aspects of principle, application, advantages, and drawbacks. Then, Ga-based liquid metals as main working electrodes in primary and secondary batteries are reviewed in terms of battery configurations, working mechanisms, and functions. Next, Ga-based liquid metals as auxiliary working electrodes in lithium and nonlithium batteries are also discussed, which work as functional self-healing additives to alleviate the degradation and enhance the durability and capacity of the battery system. After that, Ga-based liquid metals as interconnecting electrodes in multi-scenarios including photovoltaics solar cells, generators, and supercapacitors (SCs) are interpreted, respectively. The summary and perspective of Ga-based liquid metals as diverse battery materials are also focused on. Finally, it was suggested that tremendous endeavors are yet to be made in exploring the innovative battery chemistry, inherent reaction mechanism, and multifunctional integration of Ga-based liquid metal battery systems in the coming future.

关键词： liquid metals soft electrodes flexible batteries deformable energy supply devices epidermal electronics

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Preparation, characterization of sludge adsorbent and investigations on its removal of hydrogen sulfide under room

Fen LI,Tao LEI,Yanping ZHANG,Jinzhi WEI,Ying YANG

《环境科学与工程前沿（英文）》 2015年第9卷第2期页码 190-196 doi: 10.1007/s11783-014-0628-2

摘要： To recycle the sludge resource from sewage treatment plants and solve the problem of odor pollution, the sludge was converted into an adsorbent by carbonized pyrolysis and the process was optimized by orthogonal experiments. The capability for odor removal as well as the structure of the adsorbent was studied with H S as a target pollutant. The results indicate that the main factor affecting the deodorization performance of the adsorbent is the activating time. The sludge adsorbent sample SAC1 prepared under optimum conditions exhibits the best deodorization performance with a H S breakthrough time of 58 min and an iodine value nearly that of the coal activated carbon. The breakthrough time of H S is much longer than that on the coal activated carbon. On the other hand, characterization results from X-ray diffractometer (XRD), X-ray photoelectron spectrometer (XPS) and scanning electron microscope (SEM) techniques show that SAC1 is composed of mainly graphite carbon with lower oxygen content on the surface. The bulk of SAC1 exhibits a honeycomb structure with well developed porosity and a high specific surface area of 120.47 m ·g , with the average pore diameter being about 5 nm. Such a structure is in favor of H S adsorption. Moreover, SAC1 is detected to contain various metal elements such as Zn, Fe, Mg, etc., leading to a superior deodorization property to that of coal activated carbon.

关键词： orthogonal experiment sludge adsorbent hydrogen sulfide

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Room-temperature hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed

《化学科学与工程前沿（英文）》 2022年第16卷第12期页码 1782-1792 doi: 10.1007/s11705-022-2220-9

摘要： Ultra-dispersed Ni nanoparticles (7.5 nm) on nitrogen-doped carbon nanoneedles (Ni@NCNs) were prepared by simple pyrolysis of Ni-based metal–organic-framework for selective hydrogenation of halogenated nitrobenzenes to corresponding anilines. Two different crystallization methods (stirring and static) were compared and the optimal pyrolysis temperature was explored. Ni@NCNs were systematically characterized by wide analytical techniques. In the hydrogenation of p-chloronitrobenzene, Ni@NCNs-600 (pyrolyzed at 600 °C) exhibited extraordinarily high performance with 77.9 h^–1 catalytic productivity and > 99% p-chloroaniline selectivity at full p-chloronitrobenzene conversion under mild conditions (90 °C, 1.5 MPa H₂), showing obvious superiority compared with reported Ni-based catalysts. Notably, the reaction smoothly proceeded at room temperature with full conversion and > 99% selectivity. Moreover, Ni@NCNs-600 afforded good tolerance to various nitroarenes substituted by sensitive groups (halogen, nitrile, keto, carboxylic, etc.), and could be easily recycled by magnetic separation and reused for 5 times without deactivation. The adsorption tests showed that the preferential adsorption of –NO₂ on the catalyst can restrain the dehalogenation of p-chloronitrobenzene, thus achieving high p-chloroaniline selectivity. While the high activity can be attributed to high Ni dispersion, special morphology, and rich pore structure of the catalyst.

关键词： halogenated nitrobenzenes room-temperature hydrogenation Ni nanoparticles nitrogen-doped carbon nanoneedles metal–organic-framework

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室内装饰材料的标准房间/墙角火实验研究进展

杨昀,张和平,刘激扬

《中国工程科学》 2003年第5卷第4期页码 55-60

摘要：

标准房间/墙角火实验是一种全尺度火灾实验研究方法，主要用来研究室内装饰材料的火灾特性。介绍了ISO 9705房间/墙角火实验方法的原理和实验装置，以及国内外利用该方法对装饰材料火灾特性进行研究的进展情况，包括对材料热释放速率、烟气产生和室内火蔓延方面的研究。分析了其研究成果在室内装饰材料的分类及火灾危险性评估中的实际应用情况，并结合作者目前的工作对未来的研究内容做了一些展望。

关键词：装饰材料全尺度 ISO 9705 房间/墙角火实验

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三峡升船机顶部机房钢屋架设计与施工

孙昌忠

《中国工程科学》 2013年第15卷第9期页码 33-39

摘要：

根据三峡升船机顶部机房钢屋架的使用要求，研究分析了钢屋架的结构形式，通过建立三维有限元模型验证了钢屋架结构形式及其设计方案在施工阶段的结构安全性。同时，通过对钢屋架施工方案的研究，制定了适合三峡升船机顶部机房钢屋架施工作业环境的施工程序以及施工设备选型，对钢屋架施工过程中钢桁架分段、格构支撑架的设置、钢桁架吊装、中控室屋面网架安装、屋面板安装等环节提出了针对性的施工方法。三峡升船机顶部机房钢屋架所采用的结构设计方法与施工方案确保了钢屋架的顺利安装与安全运行，对类似工程具有一定的参考价值。

关键词：升船机机房钢屋架设计施工三峡工程

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含铬废水常温合成铬铁矿的结晶行为及稳定性 Article

吕晋芳, 全英聪, 童雄, 彭勇军, 郑永兴

《工程（英文）》 2022年第9卷第2期页码 67-76 doi: 10.1016/j.eng.2020.12.018

摘要：

铁氧体法不仅能净化含重金属废水，而且能从废水中回收有价金属。因此，铁氧体法被认为是一种处理含铬废水最具潜力的技术。然而，由于高的合成温度，该技术尚未在工业上得到广泛应用。本文对常温合成铬铁矿的可行性进行全面研究。考查了关键因素对出水水质、合成产物结晶行为和稳定性的影响。结果表明，经过常温铁氧体法处理后，废水中铬的去除率超过99.0%，上清液中铬的浓度达到污水排放标准。提高充气速率、搅拌速率和反应时间有利于稳定铬铁矿的形成。通过常温铁氧体法获得的颗粒结构致密，最大粒径可达52 μm。在合成过程中，铬逐渐地进入尖晶石晶体结构，合成铬铁矿的分子式为Fe_3-xCr_xO₄，其中x约0.30。为阐明常温环境下铬铁矿的合成机理，提出了微观反应路径。本研究为铁氧体法在含铬废水净化和综合利用方面的工业应用奠定了基础。

关键词：含铬废水铬铁矿合成常温结晶行为稳定性

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A nano-scale alignment method for imprint lithography

WANG Li, LU Bing-heng, DING Yu-cheng, QIU Zhi-hui, LIU Hong-zhong

《机械工程前沿（英文）》 2006年第1卷第2期页码 157-161 doi: 10.1007/s11465-006-0014-2

摘要： A novel nano-scale alignment technique based on moiré signal for room-temperature imprint lithography in the submicron realm is proposed. The moiré signals generated by two pairs of quadruple gratings on mold and wafer are optically projected onto two photo-detector arrays, then the detected moiré signals are used to estimate the alignment errors in the x and y directions. The experiment results indicate that complex differential moiré signal is sensitive to relative displacement of the mold and wafer, and the alignment accuracy obtained in the x and γ directions and in θ are 20 nm , 25 nm and 1 μrad (3σ), respectively. They can meet the requirements of alignment accuracy for submicron imprint lithography.

关键词： submicron alignment accuracy nano-scale alignment quadruple room-temperature

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Room temperature liquid metal: its melting point, dominating mechanism and applications

Junheng FU, Chenglin ZHANG, Tianying LIU, Jing LIU

《能源前沿（英文）》 2020年第14卷第1期页码 81-104 doi: 10.1007/s11708-019-0653-8

摘要： The room temperature liquid metal (LM) is recently emerging as a new class of versatile materials with fascinating characteristics mostly originated from its simultaneous metallic and liquid natures. The melting point is a typical parameter to describe the peculiarity of LM, and a pivotal factor to consider concerning its practical applications such as phase change materials (PCMs) and advanced thermal management. Therefore, the theoretical exploration into the melting point of LM is an essential issue, which can be of special value for the design of new LM materials with desired properties. So far, some available strategies such as molecular dynamics (MD) simulation and classical thermodynamic theory have been applied to perform correlative analysis. This paper is primarily dedicated to performing a comprehensive overview regarding typical theoretical strategies on analyzing the melting points. It, then, presents evaluations on several factors like components, pressure, size and supercooling that may be critical for melting processes of liquid metal. After that, it discusses applications associated with the characteristic of low melting points of LM. It is expected that a great many fundamental and practical works are to be conducted in the coming future.

关键词： melting point liquid metal crystal thermodynamics molecular dynamics

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Room temperature oxidation of acetone by ozone over alumina-supported manganese and cobalt mixed oxides

Mehraneh Ghavami, Mostafa Aghbolaghy, Jafar Soltan, Ning Chen

《化学科学与工程前沿（英文）》 2020年第14卷第6期页码 937-947 doi: 10.1007/s11705-019-1900-6

摘要： Volatile organic compounds (VOCs) are among the major sources of air pollution. Catalytic ozonation is an efficient process for removing VOCs at lower reaction temperature compared to catalytic oxidation. In this study, a series of alumina supported single and mixed manganese and cobalt oxides catalysts were used for ozonation of acetone at room temperature. The influence of augmenting the single Mn and Co catalysts were investigated on the performance and structure of the catalyst. The manganese and cobalt single and mixed oxides catalysts of the formula Mn10%-CoX and Co10%-MnX (where X= 0, 2.5%, 5%, or 10%) were prepared. It was found that addition of Mn and Co at lower loading levels (2.5% or 5%) to single metal oxide catalysts enhanced the catalytic activity. The mixed oxides catalysts of (Mn10%-Co2.5%) and (Mn10%-Co5%) led to acetone conversion of about 84%. It is concluded that lower oxidation state of the secondary metal improves ozone decomposition and oxidation of acetone.

关键词： ozone VOC manganese oxides cobalt oxides alumina support

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核电人因工程领域的发展

杨孟琢

《中国工程科学》 2002年第4卷第8期页码 12-19

摘要：

核电人因工程是核工程技术的一个组成部分，是研究人机交互作用，把人的特点引入核电工程设计，获得安全和高效的工艺设备与系统的新兴工程技术领域。结合我国走过的道路，重点论述了核电人因工程领域的形成、进展以及发展方向，同时也介绍了作者提出的人的可靠性的综合分类理论和其它研究成果。

关键词：核电人因工程控制室系统人的可靠性综合分类法

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Room temperature preparation of hydrazine-linked covalent organic frameworks coated capillaries for

《化学科学与工程前沿（英文）》 2023年第17卷第5期页码 548-556 doi: 10.1007/s11705-022-2252-1

摘要： Covalent organic frameworks (COFs) have been increasingly used in capillary electrochromatography due to their excellent characteristics. In this work, hydrazine-linked TFPB-DHzDS (TFPB: 1,3,5-tris(4-formylphenyl)benzene; DHzDS: 2,5-bis(3-(ethylthio)propoxy)terephthalohydrazide) was first synthesized by a simpler and easier method at room temperature and introduced into capillary electrochromatography as coating material. The TFPB-DHzDS coated capillaries were prepared by an in-situ growth process at room temperature. After optimizing the coating concentration and experimental conditions of capillary electrochromatography, baseline separation of two groups of polycyclic aromatic hydrocarbons was achieved based on the TFPB-DHzDS coated capillary. And the established method was used successfully to determine PAHs in natural water and soil samples. The spiked recoveries of polycyclic aromatic hydrocarbons in these samples ranged from 90.01% to 111.0%, indicating that the method is reliable and could detect polycyclic aromatic hydrocarbons in natural samples. Finally, molecular simulation was applied to study and visualize the interaction between the analytes and coating COF materials to investigate the molecular level separation mechanism further.

关键词： hydrazine-linked TFPB-DHzDS in-situ growth method open-tubular capillary electrochromatography molecular simulations